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The development of base metal electrodes that can act as active and stable oxygen generating electrodes in water electrolysis systems, especially at low pH levels, remains a challenge. The use of suspensions as electrolytes for water splitting has until recently been limited to photoelectrocatalytic approaches. A high current density (j=30 mA/cm2) for water electrolysis has been achieved at a very low oxygen evolution reaction (OER) potential (E=1.36 V vs. RHE) using a SnO2/H2SO4 suspension-based electrolyte in combination with a steel anode. More importantly, the high charge-to-oxygen conversion rate (Faraday efficiency of 88% for OER at j=10 mA/cm2 current density). Since cyclic voltammetry (CV) experiments show that oxygen evolution starts at a low, but not exceptionally low, potential, the reason for the low potential in chronoamperometry (CP) tests is an increase in the active electrode area, which has been confirmed by various experiments. For the first time, the addition of a relatively small amount of solids to a clear electrolyte has been shown to significantly reduce the overpotential of the OER in water electrolysis down to the 100 mV region, resulting in a remarkable reduction in anode wear while maintaining a high current density.
Water retention properties of wood fiber based growing media and their impact on irrigation strategy
(2024)
Distribution of water and air in growing media during ebb-and-flow irrigation depends on water storage properties (water retention curve) and water transport properties (hydraulic conductivity) of the materials. Growing media with their high number of coarse pores are known to exhibit strong hysteresis, i.e., differences in the water retention properties during drying and wetting cycles. To account for potential ecological disadvantages of peat, wood fibers are commonly used as substitutes for peat in growing media. However, the wood fibers generally have higher air capacities and hydraulic conductivities and lower water capacities compared to peat which may results in necessary adaptions of the irrigation strategy. Tools to optimize irrigation systems are physically based water transport models, such as HYDRUS-1D, which is commonly used to describe water transport in soils, but not often for growing media. In this study, white peat and pure wood fibers were used to describe differences in their water retention behavior. Water retention curves (drying cycles) and hydraulic conductivities were measured with standard analytical procedures. Hysteresis of the water retention curves was analytically determined based on their capillary rise properties. The results were used with a modified HYDRUS-1D model to test model quality against measured water contents during ebb-and-flow irrigation cycles and to optimize the irrigation strategy for the different materials. The results showed that the model quality was sufficiently good only if the strong hysteresis of the water retention curves was considered during the simulation process. Different strategies were tested to modify ebb-and-flow irrigation (irrigation frequency, irrigation duration and irrigation height) in that way that the water suction in the root zone was similar to that of the peat material. Simulation results showed that significant improvements could only be reached by increasing the flooding depth in ebb-and-flow systems to ensure an optimum water supply of plants in the wood fiber based growing media.
Wood fibers can contribute to replacing peat in growing media and thus help to protect peatlands. As domestic, renewable raw materials, they represent a sustainable option for this purpose. To date, however, wood fibers are usually used as a peat substitute at a maxi-mum of 30% (v/v). A main reason for this limitation is the insufficient microbial stability of wood fibers, which favors nitrogen immobilization and can thus impair nitrogen supply of plants. To address this drawback, in this study wood fibers were subjected to different thermal or thermal-hydrolytic treatments. Seedling tests with napa cabbage were conducted to determine whether treated wood fibers were free of phytotoxic substances. Mixtures with 50% (v/v) wood fiber and white peat each were used. In addition, three wood fiber varieties were evaluated in the cultivation of petunia. Two wood fiber proportions (30 and 60% v/v) and two nitrogen fertilization rates (common and increased supply) were included in each case. In the seedling trial with napa cabbage, no phytotoxic effects were detectable in any of the wood fiber variants investigated. However, when cultivating petunias, both shoot mass growth and number of flowers decreased with increasing wood fiber content. In substrates with a wood fiber content of 60% (v/v), plant development was inhibited so severely that the petunias no longer achieved marketable quality. Increased nitrogen fertilization was able to compensate for this negative effect only in few cases. This suggests that other factors than nitrogen limited plant growth in wood fiber-rich substrates. Among others, physical proper-ties such as the lower water capacity of wood fibers may be a cause. More in-depth investigations are still required in this regard.
Enhancing the nutritional value of pears through agronomic biofortification with iodine (Abstract)
(2024)
Introduction: Patients undergoing revision total hip surgery (RTHS) have a high prevalence of mild and moderate preoperative anemia, associated with adverse outcomes. The aim of this study was to investigate the association of perioperative allogeneic blood transfusions (ABT) and postoperative complications in preoperatively mild compared to moderate anemic patients undergoing RTHS who did not receive a diagnostic anemia workup and treatment before surgery. Methods: We included 1,765 patients between 2007 and 2019 at a university hospital. Patients were categorized according to their severity of anemia using the WHO criteria of mild, moderate, and severe anemia in the first Hb level of the case. Patients were grouped as having received no ABT, 1–2 units of ABT, or more than 2 units of ABT. Need for intraoperative ABT was assessed in accordance with institutional standards. Primary endpoint was the compound incidence of postoperative complications. Secondary outcomes included major/minor complications and length of hospital and ICU stay. Results: Of the 1,765 patients, 31.0% were anemic of any cause before surgery. Transfusion rates were 81% in anemic patients and 41.2% in nonanemic patients. The adjusted risks for compound postoperative complication were significantly higher in patients with moderate anemia (OR 4.88, 95% CI: 1.54–13.15, p = 0.003) but not for patients with mild anemia (OR 1.93, 95% CI: 0.85–3.94, p < 0.090). Perioperative ABT was associated with significantly higher risks for complications in nonanemic patients and showed an increased risk for complications in all anemic patients. In RTHS, perioperative ABT as a treatment for moderate preoperative anemia of any cause was associated with a negative compound effect on postoperative complications, compared to anemia or ABT alone. Discussion: ABT is associated with adverse outcomes of patients with moderate preoperative anemia before RTHS. For this reason, medical treatment of moderate preoperative anemia may be considered.
Background
Beta-blocker (BB) therapy plays a central role in the treatment of cardiovascular diseases. An increasing number of patients with cardiovascular diseases undergoe noncardiac surgery, where opioids are an integral part of the anesthesiological management. There is evidence to suggest that short-term intravenous BB therapy may influence perioperative opioid requirements due to an assumed cross-talk between G-protein coupled beta-adrenergic and opioid receptors. Whether chronic BB therapy could also have an influence on perioperative opioid requirements is unclear.
Methods
A post hoc analysis of prospectively collected data from a multicenter observational (BioCog) study was performed. Inclusion criteria consisted of elderly patients (≥ 65 years) undergoing elective noncardiac surgery as well as total intravenous general anesthesia without the use of regional anesthesia and duration of anesthesia ≥ 60 min. Two groups were defined: patients with and without BB in their regular preopreative medication. The administered opioids were converted to their respective morphine equivalent doses. Multiple regression analysis was performed using the morphine-index to identify independent predictors.
Results
A total of 747 patients were included in the BioCog study in the study center Berlin. 106 patients fulfilled the inclusion criteria. Of these, 37 were on chronic BB. The latter were preoperatively significantly more likely to have arterial hypertension (94.6%), chronic renal failure (27%) and hyperlipoproteinemia (51.4%) compared to patients without BB. Both groups did not differ in terms of cumulative perioperative morphine equivalent dose (230.9 (BB group) vs. 214.8 mg (Non-BB group)). Predictive factors for increased morphine-index were older age, male sex, longer duration of anesthesia and surgery of the trunk. In a model with logarithmised morphine index, only gender (female) and duration of anesthesia remained predictive factors.
Conclusions
Chronic BB therapy was not associated with a reduced perioperative opioid consumption.
Durch die Auswirkungen des Klimawandels – besonders durch Hitze – geraten viele indigene Baumarten innerhalb der nächsten 75 Jahre voraussichtlich an den Rand ihrer Existenz. Der Stadtstandort stellt eine zusätzliche Herausforderung dar, der durch menschliche Aktivitäten negativ, aber auch positiv beeinflusst werden kann. Besonders die Wasserverfügbarkeit kann durch geeignete vegetationstechnische Maßnahmen und intelligente Profilierung von Oberflächen befördert werden. Die Vegetation wird sich verändern. Mit gebietseinheimischen Genotypen und natürlicher Migration hitzeverträglicher Arten alleine lassen sich unsere Probleme nicht lösen. Wir brauchen Bäume in der Stadt, die beschatten und verdunsten.
Lösungsansätze sind die vielfältige Anpflanzung hitzeresistenter Genotypen indigener Arten, neuer, submediterraner Arten aus Süd- und Südosteuropa (assisted migration) sowie klimatoleranter Arten anderer Kontinente. Es ist allerdings davon auszugehen, dass sich diese Arten dann bei uns auch etablieren werden. Und das ist bei der durch die Eiszeiten verarmten Gehölzflora Mitteleuropas und für lebenswerte Städte auch gut so!
Dieses Fachbuch ist das Standardwerk für ein professionelles Qualitätsmanagement. Es beschreibt in kompakter und praxisnaher Form, wie Sie ein umfassendes QM in Ihrem Unternehmen aufbauen und optimieren. Sie werden damit mehr Produktsicherheit erreichen und Ihre Mitarbeiter dazu motivieren die Lebensmittelsicherheitskultur zu leben.
Neben der Beschreibung klassischer Managementsystemen gibt es auch Anregungen zu alternativen Systemen und Einblicke in die Arbeit ausgewählter anderer Länder.
Aufgrund vermuteter, negativer Folgen, welche von der Etablierung und Ausbreitung gebietsfremder Art ausgehen können, ist um die Verwendung von Zukunftsbäumen im städtischen Raum eine Diskussion entstanden. Im Rahmen einer Forschungsarbeit an der Hochschule Osnabrück wurde daher untersucht, wie die Ausbreitungstendenz einzelner Arten von Mitarbeiter*innen in Grünflächenämtern und Botanischen Garten eingeschätzt wird.
The objective of this article is to prepare for the initial certification according to IFS Global Markets Food V3 at the Landshuter Brauhaus AG private brewery at the Ellermühle site, which is expected in August 2025, and to create the basis for a potential follow-up certification according to IFS Food. The IFS Global Markets Food Program V3 is a standardized, voluntary and non-accredited assessment program for food companies, both for retail and manufacturer brand products (IFS 2023, p. 10 f.). It is based on the specifications of the Global Markets Program developed in 2008 (GFSI 2023a; VDOE 2020, p. 620).
The methodology of the target/actual analysis was used to work on the topic in order to be able to carry out a conformity check with regard to the requirements of IFS Global Markets Food V3 (see Appendix 3; IFS 2023). Observations, document analyses and employee surveys were carried out to obtain the most meaningful information possible. These have been recorded and evaluated within the target-performance analysis. A total of 65 deviations (equivalent to 53.7%) were identified at the basic level, and 60 deviations (equivalent to 82.2%) at the intermediate level. These were either processed as directly implemented corrective actions or formulated as recommendations for continuous improvement in the form of an action plan (see Appendix 15). The presentation of the action plan shows the deviations, the resulting measures, the associated responsibilities, the time period with the starting point and end point of the measures, and the current status. In addition a subdivision into "Basic" and "+Intermediate" was made for a better overview in the subsequent processing by the brewery.
A review as well as assessment of relevant requirements with regard to processes and significant violations after completion of the new building and commissioning at the Ellermühle site with regard to correlation with a potential "major" rating is recommended on the part of the operations manager or brewmaster (IFS 2023, p. 30).
Die Anforderungen an Unternehmen in Bezug auf Qualitätsmanagement, Nachhaltigkeitsmanagement sowie Arbeitssicherheit und Gesundheitsschutz sind hoch und immer weiter ansteigend. Gesetzliche Anforderungen, Anforderungen durch Managementsysteme, Anforderungen von Kunden und Anforderungen an Lieferanten stellen Unternehmen dabei vor sehr große Herausforderungen. Die integrierte Durchführung dieser unterschiedlichen Anforderungen sollte Ziel in Unternehmen sein um einen effizienten und erfolgreichen Weg zu gehen (Krieger-Güss & Hannus, 2023). Der enge Zusammenhang der Themen Qualitätsmanagement, Umwelt/ Nachhaltigkeitsmanagement und Arbeitssicherheit ist von immer entscheidender Bedeutung um in einem Unternehmen effizient arbeiten zu können (Krieger. 2008). Qualitätsmanagement bildet die Grundlage für den Aufbau von Strukturen in Unternehmen. An Nachhaltigkeit kommt kein Unternehmen vorbei und es dient der gesellschaftlichen Verantwortung mit den drei Dimensionen ökologisch, sozial und ökonomisch sowie der vierten Dimension Ernährung. Empfohlen wird die Integration der Anforderungen, die für das Thema Nachhaltigkeit von entscheidender Bedeutung sind in die Prozesse in Unternehmen. Gerade die ethische Dimension der Nachhaltigkeit hat einen engen Bezug zum Thema Arbeits- und Gesundheitsschutz. Die Einhaltung der Menschenrechte wird in der ISO 26000 gefordert und ist ebenfalls Bestandteil des Arbeitsschutzes. Des Weiteren wurde die Einhaltung der Menschenrechte und entsprechende Arbeitsbedingungen auch durch das neue Lieferkettengesetz gesetzlich festgelegt. Die vierte Dimension der Nachhaltigkeit “Ernährung” wird in Standards wie den DGE-Qualitätsstandards betrachtet und Vorgaben bezüglich der Ernährung in Gemeinschaftsverpflegungen dargelegt. Eine Kombination der unterschiedlichen Managementsysteme und die Einhaltung der gesetzlichen Anforderungen haben eine zentrale Funktion in erfolgreich agierenden Unternehmen und Gemeinschaftsverpflegungen.
Aktuell liegen noch viele Defizite in diesen Bereichen vor wie folgende Auswertungen zeigen. Im Zeitraum von 01/2023 – 09/2023 wurden in Deutschland 454 Rückrufe durchgeführt, die die Lebensmittelsicherheit gefährdet haben, wobei die meisten Rückrufe bei Obst und Gemüse erfolgt sind (siehe Abbildung 1).
The demands placed on companies in terms of up-to-date quality and sustainability management as well as health and safety measures are high and are becoming increasingly complex. Increased legal requirements, additional industry standards and derived customer requirements constantly present companies and value chains with new challenges. The integrated approach to the implementation of these different requirements has already taken place in companies in recent years. However, small businesses still find it difficult to face the complexity of requirements on their own without an accompanying consultation. Qualint is a support tool, which is currently available in the 3rd version. The tool supports companies in setting up and continuously developing their integrated management system with coordinated hybrid service bundles. The focus is on combining the fields of action of quality, environmental and sustainability management as well as occupational safety and health.The article illustrates how quality management can be used as a basis for building up digital and organizational structures in companies and value chains. The focus is on sustainability aspects and ethical requirements that are closely related to people, such as occupational health and safety. Compliance with human rights is required in ISO 26000 and is also part of occupational safety and health. Furthermore, compliance with human rights and corresponding working conditions is also regulated by the new Supply Chain Duty Act (LkSG). It shows how demands on companies have grown and how the consulting tool Qualint has developed accordingly.
The development of non-precious metal-based electrodes that actively and stably support the oxygen evolution reaction (OER) in water electrolysis systems remains a challenge, especially at low pH levels. The recently published study has conclusively shown that the addition of haematite to H2 SO4 is a highly effective method of significantly reducing oxygen evolution overpotential and extending anode life. The far superior result is achieved by concentrating oxygen evolution centres on the oxide particles rather than on the electrode. However, unsatisfactory Faradaic efficiencies of the OER and hydrogen evolution reaction (HER) parts as well as the required high haematite load impede applicability and upscaling of this process. Here it is shown that the same performance is achieved with three times less metal oxide powder if NiO/H2 SO4 suspensions are used along with stainless steel anodes. The reason for the enormous improvement in OER performance by adding NiO to the electrolyte is the weakening of the intramolecular O─H bond in the water molecules, which is under the direct influence of the nickel oxide suspended in the electrolyte. The manipulation of bonds in water molecules to increase the tendency of the water to split is a ground-breaking development, as shown in this first example.