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The development of base metal electrodes that can act as active and stable oxygen generating electrodes in water electrolysis systems, especially at low pH levels, remains a challenge. The use of suspensions as electrolytes for water splitting has until recently been limited to photoelectrocatalytic approaches. A high current density (j=30 mA/cm2) for water electrolysis has been achieved at a very low oxygen evolution reaction (OER) potential (E=1.36 V vs. RHE) using a SnO2/H2SO4 suspension-based electrolyte in combination with a steel anode. More importantly, the high charge-to-oxygen conversion rate (Faraday efficiency of 88% for OER at j=10 mA/cm2 current density). Since cyclic voltammetry (CV) experiments show that oxygen evolution starts at a low, but not exceptionally low, potential, the reason for the low potential in chronoamperometry (CP) tests is an increase in the active electrode area, which has been confirmed by various experiments. For the first time, the addition of a relatively small amount of solids to a clear electrolyte has been shown to significantly reduce the overpotential of the OER in water electrolysis down to the 100 mV region, resulting in a remarkable reduction in anode wear while maintaining a high current density.
In Deutschland werden 80% der auf Pflege angewiesenen Menschen im häuslichen Umfeld versorgt, 56 % davon aufgrund sozialer Beziehungen ausschließlich von informell pflegenden Personen. Die Anzahl häuslicher Pflegearrangements steigt seit Jahren kontinuierlich bei bereits erreichter Kapazitätsgrenze existierender ambulanter Dienste. Um einen Beitrag zum wissenschaftlichen Verständnis pflegerischer Versorgung im häuslichen Setting zu leisten, wurden insgesamt 18 narrative Interviews zu Wunsch und Wirklichkeit häuslicher Pflege mit pflegebedürftigen und pflegenden Personen sowie zwei Expert*innen geführt und nach den Prinzipien der Grounded Theory ausgewertet. Die entwickelte Akzeptanztheorie bietet einen grundsätzlichen Erklärungsansatz informeller Pflege und verweist auf die dringliche und unabdingbar notwendige Weiterentwicklung ambulanter Versorgungsstrukturen, sollen Pflegearrangements in großer Anzahl weiterhin Bestand haben.
The 3GPP release 16 integrates TSN functionality into 5G and standardizes various options for TSN time synchronization over 5G such as transparent mode and bridge mode. The time domains for the TSN network and the 5G network are kept separate with an option to synchronize either of the networks to the other. The TSN time synchronization over 5G is possible either by using the IEEE 1588 generalized Precision Time Protocol (gPTP) based on UDP/IP multicast or via IEEE 802.1AS based on Ethernet PDUs. The INET and Simu5G simulation frameworks, which are both based on the OMNeT++ discrete event simulator, are widely used for simulating TSN and 5G networks. The INET framework comprises the 802.1AS based time synchronization mechanism, and Simu5G provides the 5G user plane carrying IP PDUs. We modified the 802.1AS-based synchronization model of INET so that it works over UDP/IP. With that, it is possible to synchronize TSN slaves (connected to 5G UEs), across a 5G network, with a TSN master clock, present within a TSN network, that is connected to the 5G core network. Our simulation results show that 500 microseconds of synchronization accuracy can be achieved with the corrected asymmetric propagation delay of uplink and downlink between the gNodeB (gNB) and the User Equipment (UE). Furthermore, the synchronization accuracy can be improved if the delay difference between uplink and downlink is known.
Recent real-time networking developments have enabled ultra reliability, very low latency and high data rates in wired networks. Wireless networking developments have also shown that they can achieve very high data rates with consistency, but they still lack in providing ultra reliability and extremely low latency. Time Sensitive Networking (TSN) developments have brought these capabilities in Industry automation and Automotive industry too. Although TSN is standardized for wired networks for a long time, for wireless networks it will be standardized within the IEEE 802.11be standard for Wi-Fi and 3GPP Release 17 for 5G in the near future. This paper provides an overview of TSN in wired and wireless networks with the aim of comparing different simulators and presenting their offered functionality and shortcomings. These tools can be used to make oneself familiar with TSN algorithms, standards, and for the development and testing of time sensitive networks. Afterwards, the paper discusses open research questions for using TSN over wireless networks.
Water retention properties of wood fiber based growing media and their impact on irrigation strategy
(2024)
Distribution of water and air in growing media during ebb-and-flow irrigation depends on water storage properties (water retention curve) and water transport properties (hydraulic conductivity) of the materials. Growing media with their high number of coarse pores are known to exhibit strong hysteresis, i.e., differences in the water retention properties during drying and wetting cycles. To account for potential ecological disadvantages of peat, wood fibers are commonly used as substitutes for peat in growing media. However, the wood fibers generally have higher air capacities and hydraulic conductivities and lower water capacities compared to peat which may results in necessary adaptions of the irrigation strategy. Tools to optimize irrigation systems are physically based water transport models, such as HYDRUS-1D, which is commonly used to describe water transport in soils, but not often for growing media. In this study, white peat and pure wood fibers were used to describe differences in their water retention behavior. Water retention curves (drying cycles) and hydraulic conductivities were measured with standard analytical procedures. Hysteresis of the water retention curves was analytically determined based on their capillary rise properties. The results were used with a modified HYDRUS-1D model to test model quality against measured water contents during ebb-and-flow irrigation cycles and to optimize the irrigation strategy for the different materials. The results showed that the model quality was sufficiently good only if the strong hysteresis of the water retention curves was considered during the simulation process. Different strategies were tested to modify ebb-and-flow irrigation (irrigation frequency, irrigation duration and irrigation height) in that way that the water suction in the root zone was similar to that of the peat material. Simulation results showed that significant improvements could only be reached by increasing the flooding depth in ebb-and-flow systems to ensure an optimum water supply of plants in the wood fiber based growing media.
Wood fibers can contribute to replacing peat in growing media and thus help to protect peatlands. As domestic, renewable raw materials, they represent a sustainable option for this purpose. To date, however, wood fibers are usually used as a peat substitute at a maxi-mum of 30% (v/v). A main reason for this limitation is the insufficient microbial stability of wood fibers, which favors nitrogen immobilization and can thus impair nitrogen supply of plants. To address this drawback, in this study wood fibers were subjected to different thermal or thermal-hydrolytic treatments. Seedling tests with napa cabbage were conducted to determine whether treated wood fibers were free of phytotoxic substances. Mixtures with 50% (v/v) wood fiber and white peat each were used. In addition, three wood fiber varieties were evaluated in the cultivation of petunia. Two wood fiber proportions (30 and 60% v/v) and two nitrogen fertilization rates (common and increased supply) were included in each case. In the seedling trial with napa cabbage, no phytotoxic effects were detectable in any of the wood fiber variants investigated. However, when cultivating petunias, both shoot mass growth and number of flowers decreased with increasing wood fiber content. In substrates with a wood fiber content of 60% (v/v), plant development was inhibited so severely that the petunias no longer achieved marketable quality. Increased nitrogen fertilization was able to compensate for this negative effect only in few cases. This suggests that other factors than nitrogen limited plant growth in wood fiber-rich substrates. Among others, physical proper-ties such as the lower water capacity of wood fibers may be a cause. More in-depth investigations are still required in this regard.
Enhancing the nutritional value of pears through agronomic biofortification with iodine (Abstract)
(2024)
Mehr direkte Demokratie wagen : Volksentscheid und Bürgerentscheid: Geschichte - Praxis - Vorschläge
(2024)
Die Wahlbeteiligung sinkt, die Parteien haben immer weniger Mitglieder. Viele Bürgerinnen und Bürger kehren der Politik den Rücken zu - ein wesentlicher Grund dafür: Ob Klimaschutz oder Migration, Steuern oder Schuldenbremse, Kranken- oder Rentenversicherung ... Ständig treffen Politikerinnen und Politiker in Deutschland und Europa grundlegende Weichenstellungen, ohne dass die Bürgerinnen und Bürger darüber selbst entscheiden können. Dies soll anders werden: 42 Autorinnen und Autoren - darunter Wissenschaftlerinnen und Wissenschaftler, Politikerinnen und Politiker und Vertrauensleute von Volksbegehren in den Bundesländern - analysieren und berichten über direkte Demokratie. Insgesamt ergibt sich ein Bild, das für die Öffnung des Grundgesetzes spricht. Die Arbeit des Parlaments und der Parteien bleibt unentbehrlich - aber ergänzend sollen die Bürgerinnen und Bürger die Möglichkeit haben, durch Volksbegehren und Volksentscheid einzugreifen und punktuell politische Fragen selbst zu beantworten. Was in der Schweiz und vielen anderen europäischen Staaten, in vielen US-Gliedstaaten und in den deutschen Bundesländern und Gemeinden funktioniert, könnte auch auf Bundes- und Europaebene gegen Politikverdrossenheit helfen und Lust auf mehr politisches Engagement machen.
Die Maschine ist in der Lage faserverstärkte thermoplastische Kunststoffrohre herzustellen. Entwickelt und konstruiert wurde die Maschine als Open Source Hardware Projekt. Das bedeutet die Baupläne und Zeichnungen werden frei zur Verfügung gestellt. Heimwerker und andere Interessierte sollen dadurch die Möglichkeit bekommen faserverstärkte Rohre eigenständig und günstig herzustellen. Die Entwicklung und Konstruktion der Wickelmaschine ist das Ergebnis einer Masterarbeit an der Hochschule Osnabrück.
Introduction: Patients undergoing revision total hip surgery (RTHS) have a high prevalence of mild and moderate preoperative anemia, associated with adverse outcomes. The aim of this study was to investigate the association of perioperative allogeneic blood transfusions (ABT) and postoperative complications in preoperatively mild compared to moderate anemic patients undergoing RTHS who did not receive a diagnostic anemia workup and treatment before surgery. Methods: We included 1,765 patients between 2007 and 2019 at a university hospital. Patients were categorized according to their severity of anemia using the WHO criteria of mild, moderate, and severe anemia in the first Hb level of the case. Patients were grouped as having received no ABT, 1–2 units of ABT, or more than 2 units of ABT. Need for intraoperative ABT was assessed in accordance with institutional standards. Primary endpoint was the compound incidence of postoperative complications. Secondary outcomes included major/minor complications and length of hospital and ICU stay. Results: Of the 1,765 patients, 31.0% were anemic of any cause before surgery. Transfusion rates were 81% in anemic patients and 41.2% in nonanemic patients. The adjusted risks for compound postoperative complication were significantly higher in patients with moderate anemia (OR 4.88, 95% CI: 1.54–13.15, p = 0.003) but not for patients with mild anemia (OR 1.93, 95% CI: 0.85–3.94, p < 0.090). Perioperative ABT was associated with significantly higher risks for complications in nonanemic patients and showed an increased risk for complications in all anemic patients. In RTHS, perioperative ABT as a treatment for moderate preoperative anemia of any cause was associated with a negative compound effect on postoperative complications, compared to anemia or ABT alone. Discussion: ABT is associated with adverse outcomes of patients with moderate preoperative anemia before RTHS. For this reason, medical treatment of moderate preoperative anemia may be considered.
Background
Beta-blocker (BB) therapy plays a central role in the treatment of cardiovascular diseases. An increasing number of patients with cardiovascular diseases undergoe noncardiac surgery, where opioids are an integral part of the anesthesiological management. There is evidence to suggest that short-term intravenous BB therapy may influence perioperative opioid requirements due to an assumed cross-talk between G-protein coupled beta-adrenergic and opioid receptors. Whether chronic BB therapy could also have an influence on perioperative opioid requirements is unclear.
Methods
A post hoc analysis of prospectively collected data from a multicenter observational (BioCog) study was performed. Inclusion criteria consisted of elderly patients (≥ 65 years) undergoing elective noncardiac surgery as well as total intravenous general anesthesia without the use of regional anesthesia and duration of anesthesia ≥ 60 min. Two groups were defined: patients with and without BB in their regular preopreative medication. The administered opioids were converted to their respective morphine equivalent doses. Multiple regression analysis was performed using the morphine-index to identify independent predictors.
Results
A total of 747 patients were included in the BioCog study in the study center Berlin. 106 patients fulfilled the inclusion criteria. Of these, 37 were on chronic BB. The latter were preoperatively significantly more likely to have arterial hypertension (94.6%), chronic renal failure (27%) and hyperlipoproteinemia (51.4%) compared to patients without BB. Both groups did not differ in terms of cumulative perioperative morphine equivalent dose (230.9 (BB group) vs. 214.8 mg (Non-BB group)). Predictive factors for increased morphine-index were older age, male sex, longer duration of anesthesia and surgery of the trunk. In a model with logarithmised morphine index, only gender (female) and duration of anesthesia remained predictive factors.
Conclusions
Chronic BB therapy was not associated with a reduced perioperative opioid consumption.
Anwendungen wie ChatGPT oder WOMBO Dream machen es leicht, Studierende ohne Programmierkenntnisse für die Anwendung von künstlicher Intelligenz (KI) zu begeistern. Deshalb sind angesichts der zunehmenden Bedeutung von KI in allen Disziplinen innovative Strategien erforderlich, um Studierende ohne Programmierkenntnisse so auszubilden, dass die Anwendung von KI als Future Skill in die Studienmodule integriert werden kann. In diesem Artikel wird ein didaktisches Planungsraster für angewandte KI vorgestellt. Es orientiert sich am Prozess der KI-Programmierung (KI-Anwendungspipeline) und verknüpft KI-Konzepte mit studienrelevanten Themen. Diese Verknüpfung eröffnet einen neuen Lösungsraum und fördert das Interesse und das Verständnis für die Potenziale und Risiken von KI bei den Studierenden. Anhand einer Beispielvorlesungsreihe für Studierende der Energiewirtschaft wird gezeigt, wie KI nahtlos in den Unterricht integriert werden kann. Dafür wird das Planungsraster für angewandte KI an die Fachvorlesung angepasst. Dadurch können die Studierenden eine fachspezifische Aufgabenstellung Schritt für Schritt mit der KI-Anwendungspipeline lösen. So zeigt die Anwendung des didaktischen Planungsrasters für angewandte KI die praktische Umsetzung der theoretischen Konzepte der KI. Darüber hinaus wird eine Checkliste vorgestellt, anhand derer beurteilt werden kann, ob KI in der entsprechenden Vorlesung eingesetzt werden kann. KI als Future Skill muss von den Studierenden anhand von Anwendungsfällen erlernt werden, die für das Studienfach relevant sind. Aus diesem Grund sollte sich die KI-Ausbildung nahtlos in verschiedene Curricula einfügen lassen, auch wenn die Studierenden aufgrund ihres Studienfachs keinen Programmierhintergrund haben.