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The objective of this review is a global assessment of the economics of second‐generation biorefineries, with a focus on the use of food waste and agricultural residues for chemical production by applying biotechnological processes. Analyses are conducted on feedstock and product distribution, applied economic models, and profitability figures for the period 2013–2018. In a study of 163 articles on different biorefinery systems, the production of chemicals is identified as the second major product class, after bioenergy. Bagasse and straw are frequently analyzed second‐generation feedstocks. Based on the evaluation of 22 articles, second‐generation biorefineries producing chemicals by applying biotechnological processes proves to be economically feasible. On average, both the internal rate of return (IRR) and the return on investment (ROI) are 20% and the payback period (PP) is 6 years. The cost share of feedstock in biorefineries is between 0–50%. The price of the end product and the fermentation yields have the most impact on profitability. The processing of food waste that has industrial and municipal origins appears more economical than the processing of agricultural residues. Scientists, policy makers and entrepreneurs with an appropriate risk tolerance are advised to pay particular attention to municipal food waste and the potential economic production of carboxylic acids. For various economic issues related to biorefineries, dynamic‐deterministic models are recommended, which can be extended by a stochastic model. This review provides an initial overview of the economic feasibility of second‐generation biorefineries. Further techno‐economic analyses are required to produce statistically significant statements on key profitability figures. © 2020 The Authors. Biofuels, Bioproducts, and Biorefining published by Society of Chemical Industry and John Wiley & Sons, Ltd.
Our world and our lives are changing in many ways. Communication, networking, and computing technologies are among the most influential enablers that shape our lives today. Digital data and connected worlds of physical objects, people, and devices are rapidly changing the way we work, travel, socialize, and interact with our surroundings, and they have a profound impact on different domains,such as healthcare, environmental monitoring, urban systems, and control and management applications, among several other areas. Cities currently face an increasing demand for providing services that can have an impact on people’s everyday lives. The CityPulse framework supports smart city service creation by means of a distributed system for semantic discovery, data analytics, and interpretation of large-scale (near-)real-time Internet of Things data and social media data streams. To goal is to break away from silo
applications and enable cross-domain data integration. The CityPulse framework integrates multimodal, mixed quality, uncertain and incomplete data to create reliable, dependable information and continuously adapts data processing techniques to meet the quality of information requirements from end users. Different than existing solutions that mainly offer unified views of the data, the CityPulse framework is also equipped with powerful data analytics modules that perform intelligent data aggregation, event detection, quality
assessment, contextual filtering, and decision support. This paper presents the framework, describes ist components, and demonstrates how they interact to support easy development of custom-made applications for citizens. The benefits and the effectiveness of the framework are demonstrated in a use-case scenario
implementation presented in this paper.
Oleamide is used as a lubricant in the manufacturing and application of polypropylene (PP) medical devices. Samples of PP were prepared with 0, 1500, and 15 000 ppm oleamide content as lubricant. The samples were either left non-sterile, sterilized with ethylene oxide (ETO), γ-radiation (γ) or autoclaved (A) and stored for up to 4 weeks. To determine the oleamide bulk-to-surface distribution depending on sterilization method and storage time an extraction method and a washing technique were applied. The oleamide content was determined by gas chromatography (GC-FID) and compared with the coefficient of friction (COF). The COF dependent on the measured lubricant content at the surface. The content of lubricant on the surface depends on the type of sterilization: ETO increased the lubricant content to some extent, γ-sterilization and autoclaving reduced it. After storage, no migration of the lubricant to the surface could be detected.
Die Maschine ist in der Lage faserverstärkte thermoplastische Kunststoffrohre herzustellen. Entwickelt und konstruiert wurde die Maschine als Open Source Hardware Projekt. Das bedeutet die Baupläne und Zeichnungen werden frei zur Verfügung gestellt. Heimwerker und andere Interessierte sollen dadurch die Möglichkeit bekommen faserverstärkte Rohre eigenständig und günstig herzustellen. Die Entwicklung und Konstruktion der Wickelmaschine ist das Ergebnis einer Masterarbeit an der Hochschule Osnabrück.
A recently published study of high temperature nitridation of iron chromium aluminum alloys (FeCrAl) at 900°C in N2–H2 has redundantly shown the formation of locally confined corrosion pockets reaching several microns into the alloy. These nitrided pockets form underneath chromia islands laterally surrounded by the otherwise protective alumina scale. Chromia renders a nitrogen‐permeable defect under the given conditions and the presence of aluminum in the alloy. In light of these findings on FeCrAl, a focused ion beam–scanning electron microscope tomography study has been undertaken on an equally nitrided FeNiCrAl sample to characterize its nitridation corrosion features chemically and morphologically. The alloy is strengthened by a high number of chromium carbide precipitates, which are also preferential chromia formation sites. Besides the confirmation of the complete encapsulation of the corrosion pocket from the alloy by a closed and dense aluminum nitride rim, very large voids have been found in the said pockets. Furthermore, metallic particles comprising nickel and iron are deposited on top of the outer oxide scale above such void regions.
While developing traffic-based cognitive enhancement technology (CET), such as bike accident prevention systems, it can be challenging to test and evaluate them properly. After all, the real-world scenario could endanger the subjects’ health and safety. Therefore, a simulator is needed, preferably one that is realistic yet low cost. This paper introduces a way to use the video game Grand Theft Auto V (GTA V) and its sophisticated traffic system as a base to create such a simulator, allowing for the safe and realistic testing of dangerous traffic situations involving cyclists, cars, and trucks. The open world of GTA V, which can be explored on foot and via various vehicles, serves as an immersive stand-in for the real world. Custom modification scripts of the game give the researchers control over the experiment scenario and the output data to be evaluated. An off-the-shelf bicycle equipped with three sensors serves as a realistic input device for the subject’s movement direction and speed. The simulator was used to test two early-stage CET concepts enabling cyclists to sense dangerous traffic situations, such as trucks approaching from behind the cyclist. Thus, this paper also presents the user evaluation of the cycling simulator and the CET used by the subjects to sense dangerous traffic situations. With the knowledge of the first iteration of the user-centered design (UCD) process, this paper concludes by naming improvements for the cycling simulator and discussing further research directions for CET that enable users to sense dangerous situations better.
Power consumption has become a major design constraint, especially for battery-powered embedded systems. However, the impact of software applications is typically considered in later phases, where both software and hardware parts are close to their finalization. Power-related issues must be detected in early stages to keep the development costs low, satisfy time-to-market, and avoid cost-intensive redesign loops. Moreover, the variety of hardware components, architectures, and communication interfaces make the development of embedded software more challenging. To manage the complexity of software applications, approaches such as model-driven development (MDD) may be used. This article proposes a power-estimation approach in MDD for software application models in early development phases. A unified modeling language (UML) profile is introduced to model power-related properties of hardware components. To determine the impact of software applications, we defined two analysis methods using simulation data and a novel in-the-loop concept. Both methods may be applied at different development stages to determine an energy trace, describing the energy-related behavior of the system. A novel definition of energy bugs is provided to describe power-related misbehavior. We apply our approach to a sensor node example, demonstrate an energy bug detection, and compare the runtime and accuracy of the analysis methods.
Die Anforderungen an zukünftige Teilnehmende eines Arbeitsmarktes verändern sich. Das von Frithjof Bergmann begründete Prinzip der Neuen Arbeit (Bergmann, 2004) ist aktuell Gegenstand zahlreicher Diskussionen und Debatten über aktuelle und zukünftige Arbeitswelten. Die sich daraus ergebenden Kompetenzanforderungen passen mit der Lehre in Hochschulen wenig zusammen. Zunehmend werden agile Lernszenarien diskutiert.
Das Inverted Classroom Modell (ICM) erfreut sich seit einigen Jahren großer Beliebtheit in der Hochschullehre. Aus Studierendensicht ist die Teilnahme an einer ICM-Veranstaltung aber eine Herausforderung. Für ein erfolgreiches Lernen sind insbesondere personale Kompetenzen wie Selbstmotivation, Durchhaltevermögen und Selbstregulationskompetenz erforderlich (Pöpel & Morisse, 2019). Um diesem Umstand entgegenzuwirken, wurde vom Autor ICM mit Ideen aus Scrum für eine Informatik-Lehrveranstaltung kombiniert (siehe auch (Morisse & Heidemann, 2021)). Die Wirkung von Scrum kann sich nur entfalten, wenn die Arbeit in einzelne Sprints aufgeteilt wird und bei der Bearbeitung der Sprints auch die eigene Zusammenarbeit im Rahmen einer Retrospektive kritisch reflektiert wird. Zu diesem Zweck wird der gesamte Inhalt der Lehrveranstaltung in eine Anzahl von thematischen Blöcken aufgeteilt, die als Lehr- und Lerninhalte für die Lern-Sprints der Scrum-Umsetzung werden. Für jeden Themenblock müssen die theoretischen Inhalte erarbeitet sowie eine eigenständige Zusammenfassung formuliert werden. Ergänzend dazu wurde ein Software-Produkt definiert, in dessen Rahmen die theoretischen Inhalte einfließen konnten.
Die Durchführung eines Reviews und einer Retrospektive schließen bei Scrum einen Sprint ab. Genau dies lässt sich auch im Hochschulkontext sehr gut als Feedback-Instrument durchführen. Das Review bestand in der Inspektion der entwickelten Software. Mit der Retrospektive wird die eigene Zusammenarbeit im Team kritisch reflektiert. Ein besonderes Augenmerk verdient der kommunikative Stil zwischen Lehrenden und Studierenden. Bei einem Veranstaltungskonzept, welches getragen wird von Interaktion und Diskussion, kommt einer empathischen und wertschätzenden Kommunikation eine besondere Bedeutung zu. Das dies in der vorgestellten Veranstaltung scheinbar gelungen ist, zeigt das Zitat eines der teilnehmenden Studierenden „Ich freue mich immer auf die Review-Termine“. Zur Erinnerung: Das Review ist der Termin zur Vorstellung des erreichten Ergebnisses, also eher ein Prüfungs-Setting, bei dem Studierende ihre Arbeit präsentieren. Weitere positive Resonanzmerkmale durch die Studierenden waren die hoffnungsvollen Fragen, ob denn die Veranstaltungen im kommenden Semester auch nach ICMScrum organisiert sind.
Various overoxidized poly(1H-pyrrole) (PPy), poly(N-methylpyrrole) (PMePy) or poly(3,4-ethylenedioxythiophene) (PEDOT) membranes incorporated into an acrylate-based solid polymer electrolyte matrix (SPE) were directly electrosynthesized by a two-step in situ procedure. The aim was to extend and improve fundamental properties of pure SPE materials. The polymer matrix is based on the cross-linking of glycerol propoxylate (1PO/OH) triacrylate (GPTA) with poly(ethylene glycol) diacrylate (PEGDA) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) as a conducting salt. A self-standing and flexible polymer electrolyte film is formed during the UV-induced photopolymerization of the acrylate precursors, followed by an electrochemical polymerization of the conducting polymers to form a 3D-IPN. The electrical conductivity of the conducting polymer is destroyed by electrochemical overoxidation in order to convert the conducting polymer into an ion-exchange membrane by introduction of electron-rich groups onto polymer units. The resulting polymer films were characterized by scanning electron microscopy, cyclic voltammetry, electrochemical impedance spectroscopy, differential scanning calorimetry, thermal analysis and infrared spectroscopy. The results of this study show that the combination of a polyacrylate-matrix with ion selective properties of overoxidized CPs leads to new 3D materials with higher ionic conductivity than SPEs and separator or selective ion-exchange membrane properties with good stability by facile fabrication.